Photoemission spectroscopy is used to quantitatively determine the partial cross section of the 1β’π‘2 and 2β’π1 subshells of methane. Photoelectron spectra are recorded using a hemispherical electron analyzer and monochromatized synchrotron radiation. The corresponding emission peaks are analyzed to calculate the partial cross sections with the associated uncertainties in a photon energy range from 16.5 to 70 eV. The presented results cover this broad energy range with corresponding uncertainties and belong to the framework of photoemission orbital tomography, aiming to bridge the experimental gap between simple single atoms and complex molecular monolayers.
Themenbereich der Metrologie
Photometrie und Radiometrie
Zitierung
Kirschner, H., Gottwald, A., Kaser, H., & Richter, M. (2024). Determining partial photoemission cross sections of methane with dedicated uncertainties. Physical Review A, 109(4), 042827-1β042827-8. https://doi.org/10.1103/PhysRevA.109.042827