Zugriffsnummer 51455
Dokumenttyp Zeitschriftenartikel Open Access Hybrid
Peer Review mit Peer Review
Sprache Englisch
Titel Spectral mosaics: Composite absorption cross sections of air-broadened tetrafluoromethane with comparable uncertainty in the measured intensity over orders of magnitude
Autor(in); Institution
Domanskaya, Alexandra; 3.4, Analytische Chemie der Gasphase, PTB-Braunschweig
Berezkin, Kirill; 3.4, Analytische Chemie der Gasphase, PTB-Braunschweig
Li, Gang; 3.4, Analytische Chemie der Gasphase, PTB-Braunschweig
Bohlius, Henning; 3.4, Analytische Chemie der Gasphase, PTB-Braunschweig
Kim, Mi Eon; 3.4, Analytische Chemie der Gasphase, PTB-Braunschweig
Harrison, Jeremy; University of Leicester, Leicester, UK
Ebert, Volker; 3.4, Analytische Chemie der Gasphase, PTB-Braunschweig
Quelle/Jahr Journal of Quantitative Spectroscopy and Radiative Transfer: 311 (2023), 1 - 11
Artikelnummer 108790
ISSN 0022-4073 (print) ; 1879-1352 (online)
DOI
Verlag Amsterdam: Elsevier
Freie Schlagworte CF4 ; IR ; Vibration ; Fundamental ; Combination ; Band strength ; Integrated intensity ; Uncertainty ; Hot bands
Zusammenfassung We have obtained low-uncertainty absorption cross sections, together with explicit uncertainties for every wavenumber, for mixtures of tetrafluoromethane (CF4) with air at 296 K. The integrated intensities in the region of the two fundamental bands ν3 and ν4 as well as four combination bands, namely ν1 + ν4, ν2 + ν4, ν3 + ν4, and ν2 + ν3, were also evaluated. The expanded uncertainties are below 1.3 % for the fundamental and below 3 % for the combination bands. An intensity estimation for the forbidden ν1 band is also obtained.
Kostenfreier Zugang Open Access Hybrid
Rechteinformation CC BY 4.0 ; Creative Commons Attribution 4.0 License
Themenbereich der Metrologie Metrologie in der Chemie und Stoffeigenschaften
Forschungsprojekt 19ENV06: MetClimVOC: Metrology for climate relevant volatiles organic compounds
Förderinformationen (1) Förderername: European Commission (EC)
Förderer ID: 0000 0001 2242 8989
Förderer ID Typ: ISNI
Förderprogramm: EMPIR 2019 Environment
Titel der Förderung: 19ENV06: MetClimVOC: Metrology for climate relevant volatile organic compounds
Förderungsnummer: 19ENV06
URI der Förderung: https://www.metclimvoc.eu/

Zitierung

Domanskaya, A., Berezkin, K., Li, G., Bohlius, H., Kim, M. E., Harrison, J., & Ebert, V. (2023). Spectral mosaics: Composite absorption cross sections of air-broadened tetrafluoromethane with comparable uncertainty in the measured intensity over orders of magnitude. Journal of Quantitative Spectroscopy and Radiative Transfer, 311, 1–11. https://doi.org/10.1016/j.jqsrt.2023.108790

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