| Zugriffsnummer | 44732 |
| Dokumenttyp | Zeitschriftenartikel |
| Peer Review | mit Peer Review |
| Sprache | Englisch |
| Titel | Low- and high-temperature study of n-heptane combustion chemistry |
| Autor(in); Institution |
Ruwe, Lena; Bielefeld University, Department of Chemistry, Bielefeld, GERMANY
Cai, Liming; RWTH Aachen University, Institute for Combustion Technology, Aachen, GERMANY
Wullenkord, Julia; Bielefeld University, Department of Chemistry, Bielefeld, GERMANY
Schmitt, Steffen C.; Bielefeld University, Department of Chemistry, Bielefeld, GERMANY
Felsmann, Daniel; RWTH Aachen University, Institute for Combustion Technology, Aachen, GERMANY
Baroncelli, Martina; RWTH Aachen University, Institute for Combustion Technology, Aachen, GERMANY
Chen, Bingjie; RWTH Aachen University, Institute for Combustion Technology, Aachen, GERMANY
Moshammer, Kai; 3.3, Physikalische Chemie, PTB-Braunschweig
Hansen, Nils; Sandia National Laboratories, Combustion Research Facility, Livermore, USA
Pitsch, Heinz; RWTH Aachen University, Institute for Combustion Technology, Aachen, GERMANY
Kohse-Höinghaus, Katharina; Bielefeld University, Department of Chemistry, Bielefeld, GERMANY
|
| Quelle/Jahr | Proceedings of the Combustion Institute: 38 (2020), 1, 405 - 413 |
| ISSN | 1540-7489 (PRINT) ; 1540-7489 (ONLINE) |
| DOI | |
| Verlag | Amsterdam: Elsevier |
| Freie Schlagworte | n-Heptane ; Low-temperature combustion ; Molecular-beam mass spectrometry ; Aromatics formation ; Chemical modeling |
| Zusammenfassung | n-Heptane has been used extensively in various fundamental combustion experiments as a prototypical hydrocarbon fuel. While the formation of polycyclic aromatic hydrocarbon (PAH) in n-heptane combustion has been studied preferably in premixed flames, this study aims to investigate the combustion chemistry of n-heptane in less-studied diffusion flame and highly rich high-temperature homogeneous oxidation configurations by using a counterflow burner and a flow reactor, respectively. This work addresses the formation of higher-molecular species in the mass range up to about 160 u in both configurations. Samples are analyzed by time-of-flight (TOF) molecular beam mass spectrometry (MBMS) using electron-impact (EI) and single-photon ionization (PI). Highly resolved speciation data are reported. Laminar flow reactor experiments cover a wide temperature range. Especially the measurements at low temperatures provide speciation data of large oxygenates produced in the low-temperature oxidation of n-heptane, which are scarce in the literature. Important precursor molecules for PAH and soot formation, such as C9H8, C10H8, C11H10, and C12H8, are formed during the high-temperature combustion process in the counterflow flame, while oxygenated growth species are observed under low-temperature conditions, even at the fuel-rich equivalence ratio of φ = 4.00. Numerical modeling for both conditions is performed by using a newly developed kinetic model of n-heptane, which includes the n-heptane and PAH formation chemistry with state-of-the-art kinetic knowledge. Good agreement between model predictions and experimental data of counterflow flame and flow reactor is observed for the major species and some intermediates of n-heptane oxidation. While the concentrations of benzene and toluene measured in the counterflow burner are well-reproduced, the numerical results for flow reactor data are not satisfactory. Differences are found between the formation pathways of fulvene, from whose isomerization benzene is produced in diffusion flame and flow reactor. |
| Themenbereich der Metrologie | Metrologie in der Chemie und Stoffeigenschaften |
Zitierung
Ruwe, L., Cai, L., Wullenkord, J., Schmitt, S. C., Felsmann, D., Baroncelli, M., Chen, B., Moshammer, K., Hansen, N., Pitsch, H., & Kohse-Höinghaus, K. (2020). Low- and high-temperature study of n-heptane combustion chemistry. Proceedings of the Combustion Institute, 38(1), 405–413. https://doi.org/10.1016/j.proci.2020.07.007