| Zugriffsnummer | 34124 |
| Dokumenttyp | Zeitschriftenartikel |
| Sprache | Englisch |
| Titel | FTIR-based measurements of self-broadening and self-shift coefficients as well as line strength in the first overtone band of HCl at 1.76 µm |
| Autor(in); Institution |
Li, Gang; 3.2, Gasanalytik und Zustandsverhalten, PTB-Braunschweig
Serdyukov, Anton; 3.2, Gasanalytik und Zustandsverhalten, PTB-Braunschweig
Gisi, Michael; Universität Heidelberg, Heidelberg, GERMANY
Werhahn, Olav; 3.2, Gasanalytik und Zustandsverhalten, PTB-Braunschweig
Ebert, Volker; 3.2, Gasanalytik und Zustandsverhalten, PTB-Braunschweig
|
| Quelle/Jahr | Journal of Quantitative Spectroscopy and Radiative Transfer: 165 (2015), 76 - 87 |
| ISSN | 0022-4073 (PRINT) ; 1879-1352 (ONLINE) |
| DOI | |
| Verlag | Oxford [u.a.]: Pergamon Press |
| Freie Schlagworte | HCl ; self-induced broadening ; self-induced shift ; line intensity ; First overtone band (2-0) |
| Zusammenfassung | FTIR spectra of the 2-0 band of HCl have been measured in the 5300-5900 cm-1 spectral region at 15 different pressures (0.05 - 2.5 bar) and at a spectral resolution of 0.07 cm-1. For the first time, reliable and consistent self-induced broadening and shift coefficients for the complete HCl 2-0 band have been reported. Line intensities determined from a robust regression analysis with improved uncertainties are also presented. Compared to previous laser-based measurement for the R3 line {Ortwein et al., Applied Physics B: Lasers & Optics, 100:341-7 (2010)}, our newly measured γ_self coefficient and line intensity are 1.35% and 0.10% larger, respectively. Hartmann and Boulet {Hartmann & Boulet, JCP 113, 9000 (2000)} developed a formalism describing the relation between the shift coefficients of different vibrational bands and successfully applied to Ar-HF system. Our newly measured self-induced shift coefficients suggest that the H-B formalism is not suitable for describing the HCl-HCl collisional system. |
| Innovationscluster | Umwelt und Klima |
Zitierung
Li, G., Serdyukov, A., Gisi, M., Werhahn, O., & Ebert, V. (2015). FTIR-based measurements of self-broadening and self-shift coefficients as well as line strength in the first overtone band of HCl at 1.76 µm. Journal of Quantitative Spectroscopy and Radiative Transfer, 165, 76–87. https://doi.org/10.1016/j.jqsrt.2015.06.021